基于界面端奇异性理论的单纤维拔出试验的试件设计

在单纤维拔出试验中，由于试件的界面端存在应力奇异性，这使试验所得到的界面剪切强度数据失去合理性[1]。但从文献[1]关于微珠脱粘试验研究的结论中可以发现当基体的楔形角小于某临界角度后，微珠试件界面端应力奇异性几乎消失。由此启发我们设计出一种楔形角小于该纤维／基体系统临界角的锥面的拔出试件，这样即可以防止出现传统拔出试件在界面端的强应力奇异性，又可以避免微珠脱粘试验自身的缺陷。界面端具有任意楔形角的轴对称模型被用于分析和确定纤维／基体系统的临界角，对方程进行渐近展开和分离变量处理，根据边界条件可以得到关于特征值λ的特征方程，针对确定的纤维／基体系统可以得到特征值和楔形角的关系曲线，我们把应力奇异性指数等于-0．005时所对应的楔形角定义为临界角，以及根据临界角设计锥面拔出试件的方法。     

Global structural behaviour of thin and moderately thick monoclinic spherical shells using a mixed shear deformation model

Summary The static and dynamic responses of anisotropic spherical shells under a uniformly distributed transverse load are investigated. Analytical solutions using the mixed variational formulation are presented for spherical shells subjected to various boundary conditions. Numerical results of a refined mixed first-order shear deformation theory for natural frequencies, critical buckling, center deflections and stresses are compared with those obtained using the classical shell theory. A variety of simply-supported and clamped boundary conditions are considered and comparisons with the existing literature are made. The sample numerical results presented herein for global structural behaviour of monoclinic spherical shells should serve as references for future comparisons.     

Shear Band Formation in Fe–Cr–Mo–V–B–Si Amorphous Alloy under Nanoindentation

The formation of shear bands in Fe–Cr–Mo–V–B–Si amorphous alloy under nanoindentation Is studied. The indentation process is considered against the background of shear band formation in the amorphous material.     

ELECTROELASTIC FIELD FOR AN IMPERMEABLE ANTI-PLANE SHEAR CRACK IN A PIEZOELECTRIC CERAMICS PLATE

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Coupled Orientation and Stretching of Chains in Mesoscale Models of Polydisperse Linear Polymers in Startup of Steady Shear Flow Simulations

Polydisperse linear polymers are studied in startup of steady shear flow simulations using dissipative particle dynamics. The results show that with an increase in polydispersity the stress overshoot declines while the steady‐state stress increases. Various physical characteristics of the systems are studied including frequency of nonbonded interactions, gyration radius data, flow alignment angles, and average bond lengths. The patterns in the data suggest higher forces are necessary to orient and stretch long chain fractions in the flow direction. Relaxation modulus data prove the broad range of relaxation mechanisms in polydisperse systems. Linear viscoelasticity theory is used to quantify the relaxation spectrum. The results indicate an increase in the longest relaxation time in systems with higher polydispersity. The steady‐state shear viscosity results show higher viscosities with an increase in polydispersity at all shear‐rates. The good agreement of the characteristic behaviors of modeled polydisperse polymers with experiments is encouraging for future work.

     

Nonlinear phase field theory for fracture and twinning with analysis of simple shear

A phase field theory for coupled twinning and fracture in single crystal domains is developed. Distinct order parameters denote twinned and fractured domains, finite strains are addressed and elastic nonlinearity is included via a neo-Hookean strain energy potential. The governing equations and boundary conditions are derived; an incremental energy minimization approach is advocated for prediction of equilibrium microstructural morphologies under quasi-static loading protocols. Aspects of the theory are analysed in detail for a material element undergoing simple shear deformation. Exact analytical and/or one-dimensional numerical solutions are obtained in dimensionless form for stress states, stability criteria and order parameter profiles at localized fractures or twinning zones. For sufficient applied strain, the relative likelihood of localized twinning vs. localized fracture is found to depend only on the ratio of twin boundary surface energy to fracture surface energy. Predicted criteria for shear stress-driven fracture or twinning are often found to be in closer agreement with test data for several types of real crystals than those based on the concept of theoretical strength.     

A Three‐Factor Product Construction for Mutually Orthogonal Latin Squares

It is well known that mutually orthogonal latin squares, or MOLS, admit a (Kronecker) product construction. We show that, under mild conditions, “triple products” of MOLS can result in a gain of one square. In terms of transversal designs, the technique is to use a construction of Rolf Rees twice: once to obtain a coarse resolution of the blocks after one product, and next to reorganize classes and resolve the blocks of the second product. As consequences, we report a few improvements to the MOLS table and obtain a slight strengthening of the famous theorem of MacNeish.     

流场环境下复杂囊泡的动力学行为

采用非平衡态分子动力学方法研究了二维复杂囊泡在剪切流中的动力学行为. 模拟发现了复杂囊泡经典的翻滚(tumbling)、摇摆(trembling)和坦克履(tank-treading)行为, 还观察到由坦克履行为向平动行为(translating)的转变. 囊泡的平动行为与剪切率大小、复杂囊泡的形状密切相关. 当大囊泡均匀嫁接较多数目的小囊泡后, 其平动方式消失. 该研究有益于加深对囊泡在剪切流场中复杂性行为的理解.     

噪声情况下的量子网络直接通信

提出和研究了噪声情况下的量子网络直接通信. 通信过程中所有量子节点共享多粒子Greenberger-Horne-Zeilinger (GHZ)量子纠缠态; 发送节点将手中共享的GHZ态的粒子作为控制比特、传输秘密信息的粒子作为目标比特, 应用控制非门(CNOT)操作; 每个接收节点将手中共享GHZ 态的粒子作为控制比特、接收到的秘密信息粒子作为目标比特, 再次应用CNOT门操作从而获得含误码的秘密信息. 每个接收节点从秘密信息中提取部分作为检测比特串, 并将剩余的秘密信息应用奇偶校验矩阵纠正其中存在的比特翻转错误, 所有接收节点获得纠正后的秘密信息. 对协议安全、吞吐效率、通信效率等进行了分析和讨论.     

Progress in Developments of Inorganic Nanocatalysts for Application in Direct Methanol Fuel Cells

Significant progress has been made in the last few years toward synthesizing highly dispersible inorganic catalysts for application in the electrodes of direct methanol fuel cells. In addition, research toward achieving an efficient catalyst supporting matrix has also attracted much attention in recent years. Carbon black- (Vulcan XC-72) supported Platinum and Platinum-Ruthenium catalysts have for long served as the conventional choice as the cathode and the anode catalyst materials, respectively. Oxygen reduction reaction at the cathode and methanol oxidation reaction at the anode occur simultaneously during the operation of a direct methanol fuel cell. However, inefficiencies in these reactions result in a generation of mixed potential. This, in turn, gives rise to reduced cell voltage, increased oxygen stoichiometric ratio, and generation of additional water that is responsible for water flooding in the cathode chamber. In addition, the lack of long-term stability of Pt-Ru anode catalyst, coupled with the tendency of Ru to cross through the polymer electrolyte membrane and eventually get deposited on the cathode, is also a serious drawback. Another source of potential concern is the fact that the natural resource of Pt and the rare earth metal Ru is very limited, and has been predicted to become exhausted very soon. To overcome these problems, new catalyst systems with high methanol tolerance and higher catalytic activity than Pt need to be developed. In addition, the catalyst-supporting matrix is also witnessing a change from traditionally used carbon powder to transition metal carbides and other high-performance materials. This article surveys the recent literature based on the advancements made in the field of highly dispersible inorganic catalysts for application in direct methanol fuel cells, as well as the progress made in the area of catalyst-supporting matrices.